Advancements in Sustainable Polyester

For polyester, bio-based raw materials, emerging biodegradable products, and more efficient post-treatment processes hint towards a greener future.
90% of the world’s plastics are derived from fossil fuels, yet only about 14% are recyclable. The plastics industry is advancing toward more sustainable solutions to address this challenge. In the case of polyester, innovations such as bio-based raw materials, biodegradable alternatives, and improved recycling technologies are paving the way for sustainability.
Bio-Based Raw Materials
Typically, manufacturers synthesize polyethylene terephthalate (PET) from petroleum products, terephthalic acid, and ethylene glycol. Bio-based raw materials offer an alternative to products derived from petroleum, significantly reducing atmospheric carbon dioxide output. Manufacturers can obtain these raw materials during the growth of plants via carbon sequestration. Compared to petroleum-based PET, bio-PET manufacturing decreases greenhouse gas emissions by 82%. 30% bio-based PET is already commercially available, but 100% bio-based PET remains a long-term ambition. Advancements in catalytic systems, production processes, and declining production costs suggest bio-PET is becoming increasingly marketable.

Biomass offers an alternative to petroleum for the production of PET. Courtesy of Recycled polymer: Green roads for polyester plastics.
Biodegradable Polyesters

There are many avenues towards a greener future for polyesters, including emerging materials and future research paths. Courtesy of Recycled polymer: Green roads for polyester plastics.
Biodegradable plastics offer a promising direction for reducing and eventually eliminating plastic pollution. Microorganisms in the environment break these materials down into carbon dioxide and water. Conditions such as temperature, pH, concentration of degrading enzymes and microorganisms, and humidity can affect the rate of this process. Researchers must consider this when developing biodegradable polymers, as environmental conditions can lead to slower degradation. Recently, researchers have developed several promising biodegradable polyester materials.
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One such example is polyhydroxyalkanoates (PHAs). These materials are natural polymers synthesized by microorganisms, and they show excellent degradation and physical properties. PHA degrades in soil, seawater, and lake water, and it is also chemically recyclable. Currently, PHA is costly, rendering it only suitable for high-end medical applications. Advancements in synthetic biology technology will continue to lower this cost.
The Future of Green Polyester
As research continues and technology improves, chemists and biologists must work together to ensure a sustainable future for these materials. Dependence on foods such as grain or corn can be problematic if there is an increased demand for these resources. Choosing biomass resources such as corn straw or forestry waste can help mitigate this. Additionally, optimizing performance, degradability, recyclability, and cost savings for new materials is vital.
The green development of plastic, including polyester, shows a promising future. Bio-based raw materials and biodegradable plastics allow for a reduction of carbon emissions and lessen the industry’s dependence on petroleum. Polyester plastics are extremely pervasive, and development of sustainable polyester materials is crucial for a greener future.